What is Birefringence?What is Birefringence?

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What is Birefringence?

Gems that polarize light and split it into two (or three) different directions are said to be doubly refractive. Birefringence is a measure of a gem's double refraction. It serves as one of the principal ways gemologists can identify gems.

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gemstone birefringence - zircon
Natural zircon (not to be confused with cubic zirconia) has been used to create convincing diamond imitations. However, this gem is doubly refractive and has a high birefringence. Diamonds have no birefringence. 2.35-ct radiant step emerald-cut zircon. © Dan Stairs Custom Gemstones. Used with permission.

How Do You Measure a Gem's Refractive Index?

Gemologists calculate a gem's refractive index, or RI, by dividing the speed of light in a vacuum by the speed of light as it passes through the gem. Light slows down (or bends) whenever it enters a gemstone. Since the speed of light in a vacuum is always faster than the speed of light through any gemstone, an RI is always a number greater than 1. Gemologists use a device called a refractometer to measure a gem's RI. Since the RI ranges of gemstones have been well established, this is a valuable gem identification technique.

Which Gems Show Birefringence?

Gemstones that form in any crystal system except the isometric or amorphous are birefringent. They have two (or three) RIs based on the direction light enters them. The crystal systems that produce gems with birefringence are the tetragonal, orthorhombic, monoclinic, triclinic, hexagonal, and trigonal.

On the other hand, gems that form in the isometric or cubic crystal system, like diamonds and garnets, have only one RI since these crystals don't polarize light. They aren't doubly refractive and, thus, have no birefringence. Amorphous gems like opals also have only one RI and no birefringence.

How Do You Calculate a Gem's Birefringence?

The difference between a gemstone's highest and lowest RIs is its birefringence number. The greater that number, the more noticeable any birefringent effects will be to the naked eye. The lower the number, the less noticeable any birefringent effects will appear.

Some gemstones have ranges for RI values for each of their axes. For example, microcline, a variety of feldspar, has the following RI values:

α axis = 1.514-1.529; β axis = 1.518-1.533; and γ axis = 1.521-1.539.

In cases like these, you calculate the birefringence as a range. You take the maximum difference of the smallest values and the maximum difference of the highest values. Thus:

1.521 - 1.514 = 0.007

1.539 - 1.529 = 0.010

So, the birefringence of microcline is 0.007-0.010.

microcline - gemstone birefringence
Feldspar, variety microcline. Photo by Randolph Black. Public Domain.

What are Birefringent Effects?

Pleochroism

If gemstones with high birefringence have color, they may display pleochroism, two or three colors, such as naturally trichroic zoisite. You can see different pleochroic colors depending on your viewing angle. In contrast, colored gemstones with very low birefringence may not show pleochroism. The differences in color may be too slight to be perceived by the human eye.

Zoisite-20888
Zoisite (Var. Tanzanite), 8.5 x 4.0 x 2.0 cm, Merelani Hills (Mererani), Lelatema Mts, Arusha Region, Tanzania. © Rob Lavinsky, www.iRocks.com. Used with permission.

Fuzziness

Some doubly refractive gems may have a fuzzy, out-of-focus appearance, such as this piece of adamite.

Adamite-39492
The fuzziness in this adamite isn't a camera effect. Instead, the gem's birefringence causes this naturally. Adamite (Var: Manganoan Adamite), 3.0 x 1.5 x 1.0 cm, Ojuela Mine, Mapimi, Mun. de Mapimi, Durango, Mexico. © Rob Lavinsky, www.iRocks.com. Used with permission.

Double Images

Some gems are so birefringent that they create a double vision effect. If the stone is faceted, the facets on the opposite side of the viewer will appear to be doubled. Some gemstones, such as calcite, will create a double image of whatever lies behind it.

2756010517_d612f79cca_o
Calcite. Photo by Anders Sandberg. Licensed under CC By 2.0.

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